Toxic substances list: perfluorooctane sulfonate (PFOS), its salts and precursors
Related information
Perfluorooctane sulfonate (PFOS), its salts and its precursors are industrial chemicals that belong to the broad class of per- and polyfluoroalkyl substances (PFAS). PFAS are a class of over 4,700 human-made substances. In April 2021, the Government of Canada indicated that it is considering activities that would address PFAS as a class. Visit the PFAS web page for the latest information on publications and actions taken under the Government's Chemicals Management Plan related to PFAS.
PFOS, its salts and precursors are fluorochemicals that contain carbon atoms that are completely saturated by fluorine. It is the strength of the carbon-fluorine bonds that contributes to the extreme stability and unique properties of these perfluorinated chemicals. PFOS is a compound with a chain length containing eight perfluorinated carbon atoms (C8) bonded to a sulfonate anion moiety (SO3-).
PFOS, its salts and precursors were primarily used as a surfactant in the metal plating industry and in aqueous film-forming foam (AFFF) used in firefighting, specifically fuel fires. They have water, oil, dirt and grease repellant properties and were historically used in a wide variety of surface treatments for textiles, upholstery, leather, carpet and packaging. They were also used in electrical and electronic equipment such as semi-conductors.
For more information on these substances, please visit the Chemical Substances website and the Chemicals at a glance information sheet for PFOS, its salts and precursors.
Risk assessment
- CEPA Schedule 1 - List of Toxic Substances - These substances have been added to the List of Toxic Substances (items 84 and 85). They are entering or may enter the environment in a quantity or concentration or under conditions that have or may have an immediate or long-term harmful effect on the environment or its biological diversity.
- Final Order Adding PFOS, its salts and precursors to Schedule 1 of the Canadian Environmental Protection Act, 1999 (PDF 2.2MB, page 5) (December 2006)
- Final decision on the screening assessment of perfluorooctane sulfonate and its salts (PDF 1.9 MB, page 10) (July 2006)
- Ecological Screening Assessment Report on Perfluorooctane Sulfonate, Its Salts and Its Precursors that Contain the C8F17SO2 or C8F17SO3 or C8F17SO2N Moiety (June 2006)
- PFOS Health Canada Screening Assessment Report (PDF 198KB) (January 2006)
Risk management strategy
Strategies and actions recommended to manage risks associated with these substances:
Risk management tools
Tools developed to manage risks associated with these substances:
- Prohibition of Certain Toxic Substances Regulations, 2022 [proposed] (May 2022)
- Proposed Order Amending Schedule 3 to the Canadian Environmental Protection Act, 1999 (Export Control List) (May 2022)
- Prohibition of Certain Toxic Substances Regulations, 2012
- Regulations Amending the Prohibition of Certain Toxic Substances Regulations, 2012 (for the addition of 5 substances) (December 2016)
- CEPA Schedule 3 - Export Control List - This group of substances has been added to the Export Control List (2012)
- Export of Substances on the Export Control List Regulations
- Virtual Elimination List under section 65 of CEPA (January 2009)
- Regulations Adding Perfluorooctane Sulfonate and its Salts to the Virtual Elimination List (January 2009)
- Perfluorooctane Sulfonate and its Salts and Certain Other Compounds Regulations [repealed] (June 2008)
- Perfluorooctane Sulfonate Virtual Elimination Act (April 2008)
International engagement
For information on Canada's international engagement on these substances, please visit:
- Stockholm Convention on Persistent Organic Pollutants (POPs)
- Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade
- Great Lakes Water Quality Agreement (GLWQA)
- Protocol on Persistent Organic Pollutants (POPs) (Protocol to the UNECE Convention on Long-Range Transboundary Air Pollution (LRTAP))
- Arctic Contaminants Action Program Working Group (ACAP)
- Arctic Monitoring and Assessment Programme Working Group (AMAP)
Consultations
Consultations (past and present) on these substances:
- Proposed Prohibition of Certain Toxic Substances Regulations, 2022 (May 2022)
- Proposed Order Amending Schedule 3 to the Canadian Environmental Protection Act, 1999 (May 2022)
- Consultation document on proposed amendments to Schedule 3 (Export Control List) to the Canadian Environmental Protection Act, 1999 (March 2020)
- Consultation document on proposed amendments to the Prohibition of Certain Toxic Substances Regulations, 2012 for PFOS, PFOA, LC-PFCAs, HBCD, PBDEs, DP and DBDPE (December 2018)
- Notice of intent to amend the Prohibition of Certain Toxic Substances Regulations, 2012 published in Canada Gazette, Part I (October 2018)
- Response to comments on the proposed Regulations Amending the Prohibition of Certain Toxic Substances Regulation, 2012 (October 2016)
- Response to comments on the Consultation Document on the Examination of On-going Exemptions for PFOS its salts and certain other compounds (April 2015)
- Consultation on the update to the national implementation plan on persistent organic pollutants (April 2013)
- Consultation document - Perfluorooctane Sulfonate, its Salts and Certain Other Compounds Regulations - Examination of On-going Exemptions (January 2013)
- Proposed amendments to Schedule 3 (Export Control List) to the Canadian Environmental Protection Act, 1999 (July 2011)
- Response to Comments on the Notice of Intent to recommend export controls for perfluorooctane sulfonate, its salts (PFOS) and lindane
- Proposed Perfluorooctane Sulfonate and Its Salts and Certain Other Compounds Regulations (December 2006)
- Proposed Risk Management Strategy for Perfluorooctane Sulfonate (PFOS), Its Salts and Its Precursors (July 2006)
Other information
- Perfluorooctane sulfonate, salts and precursors: Prohibition of Certain Toxic Substances Regulations, 2012
- Factsheet on Aqueous film-forming foams and the Prohibition of Certain Toxic Substances Regulations
- PFOS in the Canadian environment
- Federal Environmental Quality Guidelines for PFOS
- Perfluorooctane sulfonate in fish and water (environmental indicator)
Contact
Chemicals Management Division
Environment and Climate Change Canada
Gatineau, QC K1A 0H3
E-mail: interdiction-prohibition@ec.gc.ca
Substances Management Information Line:
Telephone: 1-800-567-1999 (in Canada) or 819-938-3232
Fax: 819-938-3231
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